Ammonia 25% Solution CP – Identification of Product Chemical Code: CHE-A20 Chemical Name: Ammonia Solution 25% Chemical Grade: AR Chemical Formula: H₅NO Chemical Weight: 35.05 g/mol CAS No: Chemical Synonyms: Ammonia Aqueous Ammonia Water Hazards Identification REACH No: No Data Available Signal Word: Danger Supplemental Hazard Information: Additional Hazard Information: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Lachrymator. Photosensitizer. RLS CHEMICALS | 256 MAIN REEF ROAD – DENVER – JHB| +27 11 913 8060 | INFO@REFLECTASGT.CO.ZA | WWW.LABEQUIPSUPPLY.CO.ZA Ammonia 25% Solution CP – Hazards statements H302 – Harmful if swallowed. H314 – Causes severe skin burns and eye damage. H335 – May cause respiratory irritation. H400 – Very toxic to aquatic life. Ammonia 25% Solution CP – Precautionary statements P273 – Avoid release to the environment. P280 – Wear protective gloves/protective clothing/eye protection/face protection. P303 + P361 + P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 + P310 – If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a Poison center/doctor. P305 + P351 + P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P391 – Collect spillage. Ammonia 25% Solution CP – Composition of Chemical Chemical Formula: H₅NO EC No 1272/2008: No Data Available Ammonia 25% Solution CP – First Aid Measures General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance. If: Inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. If: Skin Contact: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician. If: Eye Contac: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If: Swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Important Symptoms: The most important known symptoms and effects are described in the labelling section. Immediate Medical Attention: No Data Available Firefighting Measures Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or Carbon Dioxide. Hazards Arising: No Data Available Advice for Firefighters: Wear self-contained breathing apparatus for firefighting if necessary. Info for Firefighting: No Data Available Ammonia 25% Solution CP – Accidental Release Measures Personal Precautions: Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Enviromental Precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Method for Containment: Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Handling and Storage Personal Precautions: Always open containers slowly to allow any excess pressure to vent. Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Enviromental Precautions: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. May develop pressure. Refrigerate before opening. Handle and open container with care. Exposure Controls | Personal Protection Derived No Effect Level (DNEL) Workers | Application Area | Exposure Routes | Health Effect | Value No Data Available Consumers | Application Area | Exposure Routes | Health Effect | Value No Data Available Predicted No Effect Concentration (PNEC) No Data Available Engineering Controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/Face Protection: Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166 (EU). Skin Protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Full contact Material: Butyl rubber Minimum layer thickness: 0,3 mm Break through time: 480 min. Material tested: Butoject® Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 240 min. Material tested: Dermatril® Data source: KCL GmbH, D-36124, Test method: EN 374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection: Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory Protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Physical and Chemical Properties Appearance: Colourless, pungent gas or White liquid Odour: No Data Available Odour Threshold: No Data Available pH: 11.7 at 20°C Melting Point: – 60°C Boiling Point: 27°C at 1.013 hPa Flash Point: No Data Available Evaporation: No Data Available Flammability: No Data Available Upper/Lower Flammability or Explosive Limits: Upper explosion limit: 27% (V) Lower explosion limit: 16% (V) Vapour pressure: 837 hPa at 20°C Vapour density: 1.21 – (Air = 1.0) Relative density: 0.9 g/mL at 25°C Water solubility: No Data Available Partition Coefficien: No Data Available Auto-ignition Temperature: No Data Available Decomposition Temperature: No Data Available Viscosity: No Data Available Explosive properties: No Data Available Oxidizing properties: No Data Available Other Safety Info: Relative vapour density 1.21 – (Air = 1.0) Stability and Reactivity Reactivity: No Data Available Chemical Stability: Stable under recommended storage conditions. Possibility of hazardous reactions: No Data Available Conditions to Avoid: No Data Available Incompatible Materials: Copper, Iron, Zinc Hazardous Decomposition Products: Hazardous decomposition products formed under fire conditions – Nitrogen Oxides (NOx) Other decomposition products – No Data Available Toxicological Information Acute Toxicity: LD50 Oral – Rat – 350 mg/kg Remarks: Gastrointestinal: Other changes Liver: Other changes Kidney, Ureter, Bladder: Other changes Skin Corrosion/Irritation: No Data Available Serious Eye damage | Eye Irritation: No Data Available Cell Mutagenicity: No Data Available Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity: No Data Available Specific Target Organ Toxicity – Single Exposure: No Data Available Specific Target Organ Toxicity – Repeated Exposure: No Data Available Aspiration Hazard: No Data Available Ecological Information Ecological Toxicity: Toxicity to daphnia and other aquatic invertebrates: LC50 – Daphnia magna (Water flea) – 25.4 mg/l – 48 h Ecological Persistence and degradability: No Data Available Bioaccumulative Potential: Does not bioaccumulate Mobility in Soil: No Data Available Results of PBT and vPvB Assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Other Adverse Effect: Very toxic to aquatic life Disposal Considerations Waste Treatment Methods: Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging: Dispose of as unused product. Transport Information UN Number: ADR/RID: 2672 IMDG: 2672 IATA: 2672 UN Shipping Hazard: ADR/RID: Ammonia solution IMDG: Ammonia solution IATA: Ammonia solution Transport Hazard Class: ADR/RID: 8 IMDG: 8 IATA: 8 Packaging Group: ADR/RID: III IMDG: III IATA: III Enviromental Hazards: ADR/RID: yes IMDG Marine pollutant: yes IATA: no Special Precautions: No Data Available Regulatory Information Safety, Health and environmental regulations: This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Chemical Safety Assessment: For this product a chemical safety assessment was not carried out. Additional Info: RTECS: Not available Burning sensation, cough, wheezing, laryngitis, shortness of breath, spasm, inflammation and edema of the larynx, inflammation and edema of the bronchi, pneumonitis, pulmonary edema. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes and skin. Disclaimer The information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product.
• cas_number: 1336-21-6
• synonyms: [‘Ammonia solution 25 %’, ‘Ammonia Water 25%’, ‘Ammonium Hydroxide solution 25%’]
• chemical_code: CHE-A20
• chemical_name: Ammonia Solution 25%
• chemical_grade: AR
• chemical_formula: H₅NO
• chemical_weight: 35.05 g/mol
• cas_no: 1336-21-6
• chemical_synonyms: Ammonia Aqueous Ammonia Water
• hazards_identification: {‘reach_no’: ‘No Data Available’, ‘signal_word’: ‘Danger’, ‘supplemental_hazard_information’: ‘Additional Hazard Information: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Lachrymator. Photosensitizer.’}
• hazards_statements: [‘H302 – Harmful if swallowed.’, ‘H314 – Causes severe skin burns and eye damage.’, ‘H335 – May cause respiratory irritation.’, ‘H400 – Very toxic to aquatic life.’]
• precautionary_statements: [‘P273 – Avoid release to the environment.’, ‘P280 – Wear protective gloves/protective clothing/eye protection/face protection.’, ‘P303 + P361 + P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.’, ‘P304 + P340 + P310 – If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a Poison center/doctor.’, ‘P305 + P351 + P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.’, ‘P391 – Collect spillage.’]
• composition_of_chemical: {‘chemical_formula’: ‘H₅NO’, ‘ec_no_1272_2008’: ‘No Data Available’}
• first_aid_measures: {‘general_advice’: ‘Consult a physician. Show this safety data sheet to the doctor in attendance.’, ‘if_inhaled’: ‘If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.’, ‘if_skin_contact’: ‘Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.’, ‘if_eye_contact’: ‘Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.’, ‘if_swallowed’: ‘Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.’, ‘important_symptoms’: ‘The most important known symptoms and effects are described in the labelling section.’, ‘immediate_medical_attention’: ‘No Data Available’}
• firefighting_measures: {‘extinguishing_media’: ‘Use water spray, alcohol-resistant foam, dry chemical or Carbon Dioxide.’, ‘hazards_arising’: ‘No Data Available’, ‘advice_for_firefighters’: ‘Wear self-contained breathing apparatus for firefighting if necessary.’, ‘info_for_firefighting’: ‘No Data Available’}
• accidental_release_measures: {‘personal_precautions’: ‘Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.’, ‘environmental_precautions’: ‘Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.’, ‘method_for_containment’: ‘Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.’}
• handling_and_storage: {‘personal_precautions’: ‘Always open containers slowly to allow any excess pressure to vent. Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.’, ‘environmental_precautions’: ‘Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. May develop pressure. Refrigerate before opening. Handle and open container with care.’}
• exposure_controls_personal_protection: {‘derived_no_effect_level_dnel’: {‘workers’: {‘application_area’: ‘No Data Available’, ‘exposure_routes’: ‘No Data Available’, ‘health_effect’: ‘No Data Available’, ‘value’: ‘No Data Available’}, ‘consumers’: {‘application_area’: ‘No Data Available’, ‘exposure_routes’: ‘No Data Available’, ‘health_effect’: ‘No Data Available’, ‘value’: ‘No Data Available’}}, ‘predicted_no_effect_concentration_pnec’: ‘No Data Available’, ‘engineering_controls’: ‘Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.’, ‘eye_face_protection’: ‘Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166 (EU).’, ‘skin_protection’: {‘full_contact’: {‘material’: ‘Butyl rubber’, ‘minimum_layer_thickness’: ‘0,3 mm’, ‘break_through_time’: ‘480 min.’, ‘material_tested’: ‘Butoject®’}, ‘splash_contact’: {‘material’: ‘Nitrile rubber’, ‘minimum_layer_thickness’: ‘0,11 mm’, ‘break_through_time’: ‘240 min.’, ‘material_tested’: ‘Dermatril®’}, ‘data_source’: ‘KCL GmbH, D-36124, Test method: EN 374’}, ‘body_protection’: ‘Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.’, ‘respiratory_protection’: ‘Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multipurpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).’}
• physical_and_chemical_properties: {‘appearance’: ‘Colourless, pungent gas or White liquid’, ‘odour’: ‘No Data Available’, ‘odour_threshold’: ‘No Data Available’, ‘ph’: ‘11.7 at 20°C’, ‘melting_point’: ‘– 60°C’, ‘boiling_point’: ’27°C at 1.013 hPa’, ‘flash_point’: ‘No Data Available’, ‘evaporation’: ‘No Data Available’, ‘flammability’: ‘No Data Available’, ‘upper_lower_flammability_or_explosive_limits’: {‘upper_explosion_limit’: ‘27% (V)’, ‘lower_explosion_limit’: ‘16% (V)’}, ‘vapour_pressure’: ‘837 hPa at 20°C’, ‘vapour_density’: ‘1.21 – (Air = 1.0)’, ‘relative_density’: ”}
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